シマザキ ユウイチ島崎 優一教授Yuichi SHIMAZAKI
■研究者基本情報
経歴
外部リンク
■研究活動情報
論文
- 〔主要な業績〕Diversity of oxidation state in copper complexes with phenolate ligands
Tomoyuki Takeyama; Yuichi Shimazaki, ラスト(シニア)オーサー, The Cu-phenolate complexes show various electronic structures, such as phenoxyl radical binding CuI complexes and CuIV–phenolate species in the formal oxidation state, which give rise to characteristic properties and reactivities of the complexes., Royal Society of Chemistry (RSC)
Dalton Transactions, 2024年01月, ［査読有り］, ［招待有り］ - Syntheses, Characterizations, Crystal Structures, and Protonation,Reactions of Dinitrogen Chromium Complexes Supported with,Triamidoamine Ligands
Yoshiaki Kokubo; Kazuki Tsuzuki; Hikari Sugiura; Shunsuke Yomura; Yuko Wasada-Tsutsui; Tomohiro Ozawa; Sachiko Yanagisawa; Minoru Kubo; Tomoyuki Takeyama; Takahide Yamaguchi; Yuichi Shimazaki; Shinichi Kugimiya; Hideki Masuda; and Yuji Kajita, American Chemical Society (ACS)
Inorganic Chemistry, 2023年04月, ［査読有り］ - 〔主要な業績〕Non-innocent redox behavior of Cu(II)-p-dimethylaminophenolate complexes: formation and characterization of the Cu(I)-phenoxyl radical species.
Yuto Shima; Takashi Suzuki; Hitoshi Abe; Tatsuo Yajima; Seiji Mori; Yuichi Shimazaki, ラスト(シニア)オーサー
Chem. Commun., 2022年05月, ［査読有り］ - 〔主要な業績〕Solid State Characterization of One- and Two-Electron Oxidized CuII-salen Complexes with para-Substituents: Geometric Structure-Magnetic Property Relationship
Tomoyuki Takeyama; Takashi Suzuki; Misa Kikuchi; Misato Kobayashi; Hiromi Oshita; Kyohei Kawashima; Seiji Mori; Hitoshi Abe; Norihisa Hoshino; Satoshi Iwatsuki; Yuichi Shimazaki, ラスト(シニア)オーサー
European Journal of Inorganic Chemistry, 2021年10月, ［査読有り］ - 〔主要な業績〕Formation of the Ni(II)-Phenoxyl Radical Complexes by O2: A Mechanistic Insight into the Reaction of Ni(II)-Phenol Complexes with O2
Takashi Suzuki; Akari Sato; Hiromi Oshita; Tatsuo Yajima; Fumito Tani; Hitoshi Abe; Kaoru Mieda-Higa; Sachiko Yanagisawa; Takashi Ogura; Yuichi Shimazaki, ラスト(シニア)オーサー,The reaction of Ni(
, Royal Society of Chemistry (RSC)ii )-(phenol)(phenolate) complexes with O2 gave the Ni(ii )-phenoxyl radical complexes assisted by CH3OH. This reaction was concluded to undergovia the proton transfer–electron transfer type mechanism without redox of the Ni ion.
Dalton Trans., 2021年03月, ［査読有り］ - Recent Advances in One-electron Oxidized CuII-Diphenoxide Complexes as Models of Galactose Oxidase: Importance of the Structural Flexibility in the Active Site
Hiromi Oshita; Yuichi Shimazaki, ラスト(シニア)オーサー
Chem. Eur. J., 2020年07月08日, ［査読有り］, ［招待有り］ - Benzyl alcohol oxidation mechanisms by one- and two-electron oxidized species of Cu(II)-salen complexes with para-R-substituents, [Cu(R-salen)]n+ (R = MeO, MeS; n = 1, 2)
責任著者
Inorganica Chimica Acta, 2020年06月24日, ［査読有り］ - Formation of the CuII-phenoxyl radical by reaction of O2 with the CuII-phenolate complex via the CuI-phenoxyl radical
Takashi Suzuki; Hiromi Oshita; Tatsuo Yajima; Fumito Tani; Hitoshi Abe; Yuichi Shimazaki
Chem. Eur. J., 2019年11月, ［査読有り］ - The effect of π–π stacking interaction of the indole ring with the coordinated phenoxyl radical in a nickel(II)-salen type complex. Comparison with the corresponding Cu(II) complex
Hiromi Oshita; Takashi Suzuki; Kyouhei Kawashima; Hitoshi Abe; Fumito Tani; Seiji Mori; Tatsuo Yajima; Yuichi Shimazaki
Dalton Trans., 2019年08月, ［査読有り］ - π-π Stacking Interaction in an Oxidized Cu(II)-salen Complex with a Side Chain Indole Ring. An Approach to the Function of the Tryptophan in the Active Site of Galactose Oxidase
Hiromi Oshita; Takashi Suzuki; Kyouhei Kawashima; Hitoshi Abe; Fumito Tani; Seiji Mori; Tatsuo Yajima; Yuichi Shimazaki
Chem. Eur. J., 2019年06月, ［査読有り］ - Electronic Structure and Reactivity Studies of a Nonsymmetric One-Electron Oxidized CuII Bis-phenoxide Complex
Linus Chiang; Erik C. Wasinger; Yuichi Shimazaki; Victor Young; Jr.e Tim Storr; T. Daniel; P. Stack
Inorg. Chim. Acta, 2018年, ［査読有り］ - Characterization of the one‑electron oxidized Cu(II)‑salen complexes with a side chain aromatic ring: the effect of the indole ring on the Cu(II)‑phenoxyl radical species
Hiromi Oshita; Takayoshi Yoshimura; Seiji Mori; Fumito Tani; Yuichi Shimazaki; Osamu Yamauchi
J. Bio Inorg. Chem., 2018年01月, ［査読有り］, ［招待有り］ - Characterization of Group 10-Metal-p-Substituted Phenoxyl Radical Complexes with Schiff Base Ligands.
Hiromi Oshita; Misa Kikuchi; Kaoru Mieda; Takashi Ogura; Takayoshi Yoshimura; Fumito Tani; Tatsuo Yajima; Hitoshi Abe; Seiji Mori; Yuichi Shimazaki
CHEMISTRYSELECT, 2017年10月, ［査読有り］ - Electronic Structure Evaluation of an Oxidized Tris(methoxy)-Substituted Ni Salen Complex
Linus Chiang; Ryan M. Clarke; Khrystyna Herasymchuk; Mathew Sutherland; Kathleen E. Prosser; Yuichi Shimazaki; Tim Storr
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016年01月 - Asymmetric Michael addition of thiols to beta-nitrostyrenes using a novel phenylpyrrolidine-based urea catalyst
Souichirou Kawazoe; Kazuki Yoshida; Yuichi Shimazaki; Takeshi Oriyama
Tetrahedron Letters, 2015年, ［査読有り］ - Properties of the indole ring in metal complexes. A comparison with the phenol ring,
Y. Shimazaki; O. Yamauchi
J. Inorg. BioChem., 2015年, ［査読有り］, ［招待有り］ - Properties of the One-Electron Oxidized Copper(II) Salen-Type Complexes: Relationship between Electronic Structures and Reactivities
Yuichi Shimazaki
Pure and Applied Chemistry, 2014年, ［査読有り］, ［招待有り］ - Kinetic studies on cyclopalladation in,palladium(II) complexes containing an indole,moiety
Satoshi Iwatsuki; Takuya Suzuki; Syogo Tanooka; Tatsuo Yajima and Yuichi Shimazaki
Pure and Applied Chemistry, 2014年, ［査読有り］, ［招待有り］ - Characterization of One-Electron Oxidized Copper(II)-Salophen-Type Complexes; Effects of Electronic and Geometrical Structures on Reactivities
Kazutaka Asami; Akiko Takashina; Misato Kobayashi; Satoshi Iwatsuki; Tatsuo Yajima; Amélie Kochem; Maurice van Gastel; Fumito Tani; Takamitsu Kohzuma; Fabrice Thomas and Yuichi Shimazaki
Dalton Trans., 2014年, ［査読有り］ - FeIII Bipyrrolidine Phenoxide Complexes and Their Oxidized,Analogues
Linus Chiang; Didier Savard; Yuichi Shimazaki; Fabrice Thomas; and Tim Storr
Inorg. Chem., 2014年, ［査読有り］ - Symmetric Urea-Catalyzed Asymmetric Michael Addition of Thiols to β-Nitrostyrenes
Souichirou Kawazoe; Kazuki Yoshida; Yuichi Shimazaki; Takeshi Oriyama
Chem. Lett., 2014年, ［査読有り］ - Influence of Ligand Flexibility on the Electronic Structure of Oxidized NiIII-Phenoxide Complexes
Minoru Kawai; Takahide Yamaguchi; Shigeyuki Masaoka; Fumito Tani; Takamitsu Kohzuma; Linus Chiang; Tim Storr; Kaoru Mieda; Takashi Ogura; Robert K. Szilagyi; Yuichi Shimazaki
Inorg. Chem., 2014年, ［査読有り］ - Pd–C bond formation with the indole ring in palladium complexes of N,N,O-donor ligands. Effect of the nitrogen donor properties
Syogo Tanooka; Takuya Suzuki; Tatsuo Yajima; Tadashi Shiraiwa; Satoshi Iwatsuki; Yuichi Shimazaki
Inorganica Chimica Acta, 2013年10月, ［査読有り］ - Double oxidation localizes spin in a Ni bis-phenoxyl radical complex
Tim J. Dunn; Michael I. Webb; Khatera Hazin; Pratik Verma; Erik C. Wasinger; Yuichi Shimazaki and Tim Storr, Royal Society of Chemistry
Dalton Trans., 2013年, ［査読有り］ - Recent Advances in X-ray Structures of Metal-Phenoxyl Radical Complexes
Yuichi Shimazaki
Advances in Materials Physics and Chemistry (Review), 2013年, ［査読有り］, ［招待有り］ - One-Electron Oxidized Copper(II) Salophen Complexes: Phenoxyl versus Diiminobenzene Radical Species
Amélie Kochem; Olivier Jarjayes; Benoit Baptiste; Christian Philouze; Hervé Vezin; Kazuaki Tsukidate; Fumito Tani; Maylis Orio; Yuichi Shimazaki; Fabrice Thomas
Chem. Eur. J., 2012年, ［査読有り］ - Supramolecular Structures of Inclusion Complexes of Cyclic Porphyrin Dimers and [6,6]-Phenyl-C 61-Butyric Acid Methyl Ester (PCBM)
Hirofumi Nobukuni; Takuya Kamimura; Hidemitsu Uno; Yuichi Shimazaki; Yoshinori Naruta; Fumito Tani
Bull. Chem. Soc. Jpn., 2012年, ［査読有り］ - Synthesis, Characterization, and Small Hydrocarbon Encapsulation of Dicavitand-Porphyrins
Jun Nakazawa; Jun Hagiwara; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Bull. Chem. Soc. Jpn., 2012年, ［査読有り］ - Synthesis and properties of charge-transfer solids with cluster units [Mo6X14]2 (X . Br, I)
Gunzi Saito; Hidemasa Hosoda; Yukihiro Yoshida; Jun Hagiwara; Kazukuni Nishimura; Hideki Yamochi; Akihiro Otsuka; Takaaki Hiramatsu; Yuichi Shimazaki; Kaplan Kirakci; Stephane Cordier; Christiane Perrin
J. Mater. Chem., 2012年, ［査読有り］ - Non-innocent ligand behaviour of a bimetallic Cu complex employing a bridging catecholate.
Tim J Dunn; Linus Chiang; Caterina F Ramogida; Michael I Webb; Didier Savard; Miyuki Sakaguchi; Takashi Ogura; Yuichi Shimazaki; Tim Storr
Dalton trans., 2012年, ［査読有り］ - Group-10 metal complexes of biological molecules and related ligands: structural and functional properties
Yuichi Shimazaki; Osamu Yamauchi
Chemistry & biodiversity(Review), 2012年, ［査読有り］, ［招待有り］ - Radical Localization in a Series of Symmetric Ni(II) Complexes with Oxidized Salen Ligands.
Linus Chiang; Amélie Kochem; Olivier Jarjayes; Tim J Dunn; Hervé Vezin; Miyuki Sakaguchi; Takashi Ogura; Maylis Orio; Yuichi Shimazaki; Fabrice Thomas; Tim Storr
Chem. Eur. J., 2012年, ［査読有り］ - New Insights into the Electronic Structure and Reactivity of One-Electron Oxidized Copper(II)-(Disalicylidene)diamine Complexes.
Kazutaka Asami; Kazuaki Tsukidate; Satoshi Iwatsuki; Fumito Tani; Satoru Karasawa; Linus Chiang; Tim Storr; Fabrice Thomas; Yuichi Shimazaki
Inorg.Chem., 2012年, ［査読有り］ - Recent advances in metal-phenoxyl radical chemistry
Y. Shimazaki; O. Yamauchi
Ind. J. Chem. A. (Review), 2011年, ［査読有り］, ［招待有り］ - Influence of the chelate effect on the electronic structure of one-electron oxidized group 10 metal(II)-(disalicylidene)diamine complexes
Yuichi Shimazaki; Natsumi Arai; Tim J. Dunn; Tatsuo Yajima; Fumito Tani; Caterina F. Ramogida; Tim Storr
DALTON TRANSACTIONS, 2011年, ［査読有り］ - Non-Innocent Ligand Behavior of a Bimetallic Ni Schiff-Base Complex Containing a Bridging Catecholate
Tim J. Dunn; Caterina F. Ramogida; Curtis Simmonds; Alisa Paterson; Edwin W. Y. Wong; Linus Chiang; Yuichi Shimazaki; and Tim Storr
Inorg. Chem., 2011年, ［査読有り］ - Concentration-dependent palladium(II)–indole bond formation in complexes with a 2N-donor ligand containing an indole moiety: Synthesis, characterization, and reaction analysis
Satoshi Iwatsuki; Takuya Suzuki; Tatsuo Yajima; Tadashi Shiraiwa; Osamu Yamauchi; Yuichi Shimazaki
Inorg.Chim.Acta, 2011年, ［査読有り］ - Supramolecular Structures of Inclusion Complexes of C70 and Cyclic Porphyrin Dimers
Hirofumi Nobukuni; Takuya Kamimura; Hidemitsu Uno; Yuichi Shimazaki; Yoshinori Naruta; Fumito Tani
Bulletin of the Chemical Society of Japan, 2011年, ［査読有り］ - Unprecedented formation of binuclear copper(II) complex with a perylene derived ligand by the oxidative reaction
J. Hagiwara; Y. Shimazaki; G. Saito
Inorg. Chim. Acta, 2010年, ［査読有り］ - Ligand Radical Localization in a Nonsymmetric One-Electron Oxidized Ni(II) Bis-phenoxide Complex
T. Storr; P. Verma; Y. Shimazaki; E. C. Wasinger; T. D. P. Stack
Chem. Eur. J., 2010年, ［査読有り］ - Supramolecular Structures and Photoelectronic Properties of the Inclusion Complex of a Cyclic Free-Base Porphyrin Dimer and C60
H. Nobukuni; Y. Shimazaki; H. Uno; Y. Naruta; K. Ohkubo; T. Kojima; S. Fukuzumi; S. Seki; H. Sakai; T. Hasobe and F. Tani
Chem. Eur. J., 2010年, ［査読有り］ - Metal Complexes involving indole rings: Structure and effects of metal-indole interaction
Yuichi Shimazaki; Tatsuo Yajima; Masako Takani; Osamu Yamauchi.
Coord. Chem. Rev., 2009年, ［査読有り］, ［招待有り］ - Synthesis and Characterization of platinum(II) complexes of 2N10-donor ligands with a pendent indole ring
Yuichi Shimazaki; Tatsuo Yajima; Yasuo Nakabayashi; Yoshinori Naruta; Osamu Yamauchi.
Inorg. Chim. Acta, 2009年, ［査読有り］ - Zinc(II)-phenoxyl radical complexes: Dependence on complexation properties of Zn-phenolate species
Yuichi Shimazaki; Tatsuo Yajima; Tadashi Shiraiwa; Osamu Yamauchi.
Inorg. Chim. Acta, 2009年, ［査読有り］ - Metal complexes of amino acids and amino acid side chain groups. Structure and properties.
Yuichi Shimazaki; Masako Takani; Osamu Yamauchi
Dalton Trans.(perspective), 2009年, ［査読有り］, ［招待有り］ - Detailed Evaluation of the Geometric and Electronic Structures of One-electron Oxidized Group 10 (Ni, Pd, and Pt) Metal(II)-(Disalicylidene)diamine Complexes
Yuichi Shimazaki; T. Daniel P. Stack; Tim Storr
Inorg. Chem., 2009年, ［査読有り］ - Anisotropic High Electron Mobility and Photodynamics of a Self-Assembled Porphyrin Nanotube including C60 Molecules
Hirofumi Nobukuni; Fumito Tani; Yuichi Shimazaki; Yoshinori Naruta; Kei Ohkubo; Tatsuaki Nakanishi; Takahiko Kojima; Shunichi Fukuzumi; Shu Seki
J. Phys. Chem. C, 2009年, ［査読有り］ - CH•••Metal(II) axial interaction in planar complexes (metal = Cu, Pd) and implications for possible environmental effects of alkyl groups at biological copper site
Osamu Yamauchi; Tatsuo Yajima; Rie Fujii; Yuichi Shimazaki; Masanobu Yabusaki; Masako Takani; Minoru Tashiro; Takeshi Motoyama; Mitsuhiro Kakuto; Yasuo Nakabayashi
J. InorgBio. Chem., 2008年, ［査読有り］ - A simple preparation of d-alloisoleucine via acetylation and separation of the ammonium salts
Tatsuo Yajima; Takao Horikawa; Nobuhiro Takeda; Eri Takemura; Hiroaki Hattori; Yuichi Shimazaki; Tadashi Shiraiwa
Tetrahedron Assymetry, 2008年, ［査読有り］ - Defining the Electronic and Geometric Structure of One-Electron Oxidized Copper-Bis-phenoxide Complexes
Tim Storr; Pratik Verma; Russell C. Pratt; Eric. C. Wasinger; Yuichi Shimazaki; T. Daniel P. Stack
J. Am. Chem. Soc., 2008年, ［査読有り］ - - Stacking assisted binding of aromatic amino acids by copper(II)-aromatic diimine complexes. Effects of ring substituents on ternary complex stability
Tatsuo Yajima; Reiko Takamido; Yuichi Shimazaki; Akira Odani; Yasuo Nakabayashi; Osamu Yamauchi
Dalton Trans., 2007年, ［査読有り］ - Syntheses and Electronic Structures of One-Electron-Oxidized Group 10 Metal(II)-(Disalicylidene)diamine Complexes (Metal = Ni, Pd, Pt)
Yuichi Shimazaki; Tatsuo Yajima; Fumito Tani; Satoru Karasawa; Koichi Fukui; Yoshinori Naruta; Osamu Yamauchi
J. Am. Chem. Soc., 2007年, ［査読有り］ - Synthesis and characterization of imidazolate-bridged polynuclear copper complexes
Takumi Higa; Masaki Moriya; Yuichi Shimazaki; Tatsuo Yajima; Fumito Tani; Satoru Karasawa; Motohiro Nakano; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chim. Acta, 2007年 - Formation and Characterization of Co(III)-Semiquinonate Phenoxyl Radical Species
Yuichi Shimazaki; Ryota Kabe; Stefan Huth; Fumito Tani; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chem., 2007年, ［査読有り］ - A Nanotube of Cyclic Porphyrin Dimer Connected by Nonclassical Hydrogen Bonds and Its Inclusion of C60 in a Linear Arrangement
Hirofumi Nobukuni; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Angew. Chem. Int. Ed., 2007年, ［査読有り］ - Synthesis Crystal Structures and Single Small Molecule Encapsulation Properties of Cavitand-Porphyrin
Jun Nakazawa; Maki Mizuki; Jun Hagiwara; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Bull. Chem. Soc. Jpn., 2006年, ［査読有り］ - Encapsulation of Small Molecules by a Cavitand Porphyrin Self-Assenbled via Quadruple Hydrogen Bonds
Jun Nakazawa; Maki Mizuki; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Org. Lett., 2006年, ［査読有り］ - Selective formation of a stable -peroxo ferric heme-CuII complex from the corresponding -oxo FeIII-CuII species with hydrogen peroxide
Takefumi Chishiro; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Chem. Commun., 2005年02月, ［査読有り］ - Size-Selective and Reversible Encapsulation of Single Small Hydrocarbon Molecules by a Cavitand-Porphyrin Species
Jun Nakazawa; Jun Hagiwara; Maki Mizuki; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Angew. Chem. Int. Ed., 2005年, ［査読有り］ - Cyclopalladation of the Indole Ring in Palladium(II) Complexes of 2N1O Donor Ligands and Its Dependence on the O-Donor Properites
Yuichi Shimazaki; Minoru Tashiro; Takeshi Motoyama; Satoshi Iwatsuki; Tatsuo Yajima; Yasuo Nakabayashi; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chem., 2005年, ［査読有り］ - Characterization of Dinuclear MnV=O Complex and Its Efficient O2 Evolution in the Presence of Water
Yuichi Shimazaki; Taro Nagano; Hironori Takesue; Bao-Hui Ye; Fumito Tani; Yoshinori Naruta
Angew. Chem. Int. Ed., 2004年, ［査読有り］ - Reactivity of the Indole Ring in Palladium(II) Complexes of 2N1O-Donor Ligands: Cyclopalladation and -Cation Radical Formation
Takeshi Motoyama; Yuichi Shimazaki; Tatsuo Yajima; Yasuo Nakabayashi; Yoshinori Naruta; Osamu Yamauchi
J. Am. Chem. Soc., 2004年, ［査読有り］ - Nickel(II)-Phenoxyl Radical Complexes: Structure-Radical Stability Relationship
Yuichi Shimazaki; Stefan Huth; Satoru Karasawa; Shun Hirota; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chem., 2004年, ［査読有り］ - Intramolecular Rearrangement for Regioselective Complexation Delived from Intramolecular CH/ Interaction in a Hydrophobic Ruthenium Coordination Sphere
Takahiko Kojima; Sousi Miyazaki; Ken-ichi Hayashi; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta; Yoshihisa Maeda
Chem. Eur. J., 2004年, ［査読有り］ - An Active-Site Model of Prostaglandin H Synthase: Iron “Twin Coronet” Porphyrin with an Aryloxyl Radical and Its Catalytic Oxygenation of 1,4-Diene
Eiki Matsui; Yoshinori Naruta; Fumito Tani; Yuichi Shimazaki
Angew. Chem. Int. Ed., 2003年 - Isolation and Crystal Structure of a Peroxo-Bridged Heme-Copper Complex
Takefumi Chishiro; Yuichi Shimazaki; Fumito Tani; Yoshimitzu Tachi; Yoshinori Naruta; Satoru Karasawa; Shinya Hayami; Yonezo Maeda
Angew. Chem. Int. Ed., 2003年, ［査読有り］ - One-electron Oxidized Nickel(II)-Di(salicylidene)diamine Complexes: Temperature Dependent Tautomerism between Ni(III)-Phenolate and Ni(II)-Phenoxyl Radical States
Yuichi Shimazaki; Fumito Tani; Koichi Fukui; Yoshinori Naruta; Osamu Yamauchi
J. Am. Chem. Soc., 2003年, ［査読有り］ - Studies on galactose oxidase active site model complexes:effects of ring substituents on Cu(II)-phenoxyl radical formation
Yuichi Shimazaki; Stefan Huth; Shun Hirota; Osamu Yamauchi
Inorg. Chim. Acta, 2002年, ［査読有り］ - Conformational preference of the side chain aromatic ring in Cu(II) and Pd(II) complexes of 2N1O-donor ligands
Tatsuo Yajima; Yuichi Shimazaki; Naoya Ishigami; Akira Odani; Osamu Yamauchi
Inorg. Chim. Acta, 2002年, ［査読有り］ - Synthesis and Characterization of the Dicobalt Bisporphyrin Complex Linked by 1, 2-phenylene Bridged
Yuichi Shimazaki; Hironori Takesue; Takefumi Chishiro; Fumito Tani; Yoshinori Naruta
Chem. Lett., 2001年, ［査読有り］ - Effects of a Side Chain Aromatic Ring on the Reactivity of Copper(I) complexes with Dioxygen
Yuichi Shimazaki; Takeo Nogami; Fumito Tani; Akira Odani; Osamu Yamauchi
Angew. Chem. Int. Ed., 2001年, ［査読有り］ - 2-(Imidazol-1-yl)-4-methylphenol
Yoshinori Naruta; Yoshimitzu Tachi; Takefumi Chishiro; Yuichi Shimazaki; Fumito Tani
Acta Crystallogr., Sect E, 2001年, ［査読有り］ - Chemical Approach to the Cu(II)-Phenoxyl Radical Site in Galactose Oxidase: Dependence of the Radical Stability on N-Donor Properties
Yuichi Shimazaki; Stefan Huth; Shun Hirota; Osamu Yamauchi
Bull. Chem. Soc. Jpn., 2000年, ［査読有り］ - A Structure Model for Galactose Oxidase Active Site and Counteranion-Dependent Phenoxyl Radical Formation by Disproportionation
Yuichi Shimazaki; Stefan Huth; Akira Odani; Osamu Yamauchi
Angew. Chem. Int. Ed., 2000年, ［査読有り］ - Synthesis and Characterization of Imidazolate-Bridged Dinuclear Complexes as Active Site Models of Cu,Zn-SOD
Hideki Ohtsu; Yuichi Shimazaki; Akira Odani; Osamu Yamauchi; Wasuke Mori; Shinobu Itoh; Shunichi Fukuzumi
J. Am. Chem. Soc., 2000年, ［査読有り］ - Chemical Approach to the Cu(II)-Phenoxyl Radical Site in A novel imidazolate-bridged copper-zinc heterodinuclear complex as a Cu,Zn-SOD active site model
Hideki Ohtsu; Yuichi Shimazaki; Akira Odani; Osamu Yamauchi
Chem. Commun., 1999年12月, ［査読有り］ - Copper(I) Complexes with a Prooxymal Aromatic Ring: Novel Copper-Indole Bonding
Yuichi Shimazaki; Hiroshi Yokoyama; Osamu Yamauchi
Angew. Chem. Int. Ed., 1999年, ［査読有り］
MISC
- One-electron oxidized Cu(II)-di(phenolate) complexes; Relationship between electronic structures and reactivities
Yuichi Shimazaki
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2014年08月 - フラーレン類を包接した環状ポルフィリン二量体の超分子構造とその光・電子物性
信国浩文; 谷文都; 島崎優一; 成田吉徳; 大久保敬; 中西達昭; 小島隆彦; 福住俊一; 関修平; 宇野英満
基礎有機化学討論会要旨集, 2009年09月18日 - INOR 757-Investigation of the locus of oxidation and spectroscopic features of oxidized copper and nickel bis-phenoxide complexes
Tim Storr; Erik C. Wasinger; Russell Pratt; Yuichi Shimazaki; T. Daniel P. Stack
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008年08月
書籍等出版物
- 〔主要な業績〕大学生 これから学ぶ化学
速水真也・黒岩敬太・島崎優一・大久保貴志・折山 剛・西野 宏・須藤 篤, 共著
培風館, 2023年05月19日
9784563046422 - 錯体化合物事典
島崎優一, 分担執筆
朝倉書店, 2019年09月10日
9784254141054 - Recent Advances in the Field of Phenoxyl Radical–Metal Complexes in The Chemistry of Metal Phenolates (Volume 2)
Yuichi Shimazaki, 共著
John Wiley & Sons, Ltd, 2016年09月19日 - The Chemistry of Metal-Phenolates
Yuichi Shimazaki; Ed. J. Zabicky, 単著
John Wiley & Sons, Ltd, 2014年04月04日
9780470973585 - Electrochemistry
単著
INTECH, 2013年02月 - ベーシックマスター 無機化学
増田秀樹・長嶋雲兵 共編, 共著
オーム社, 2010年10月15日
9784274209215
講演・口頭発表等
- 酸素分子を用いた銅(II)-フェノキシド錯体の酸化反応にみられる側鎖インドール基の分子内相互作用による安定化
三輪百々花; 金城星彦; 島崎優一
日本化学会第 105 春季年会, 2025年03月28日
20250326, 20250329 - 銅(II)-フェノキシルラジカル錯体による第一級アルコールの触媒的酸化とその反応機構
吉井万里奈; 島崎優一
日本化学会第 105 春季年会, 2025年03月27日
20250326, 20250329 - 酸素分子による銅(II)-フェノキシルラジカル錯体を触媒としたベンジルアルコールの酸化触媒の構築
吉井 万里奈; 島崎 優一
第57回酸化反応討論会, 2024年11月16日
20241116, 20241117 - Reaction of Cu(II)-phenolate with O2: Formation of Cu(II)-phenoxyl radical via the Cu(I)-phenoxyl radical species
Yuichi ShImazaki
The 17th European Biological Inorganic Chemistry Conference (EuroBIC-17), 2024年08月27日
20240825, 20240929 - p-ジメチルアミノフェノラート配位子を有するコバルト錯体の原子価異性
金城星彦; 島崎優一
錯体化学会第74回討論会, 2024年09月20日
20240918, 20240920 - The role of a side-chain indole group for formation of Cu(II)-phenoxyl radical by Cu(II)-phenolate and O2
Hoshihiko Kaneshiro; Yuichi Shimazaki
The 17th European Biological Inorganic Chemistry Conference (EuroBIC-17), 2024年08月26日
20240825, 20240829 - 大気下における銅(II) -フェノキシルラジカル錯体を用いた第一級アルコールの触媒的酸化
吉井 万里奈; 島崎 優一
日本化学会 第104回春季年会, 2024年03月20日
20240318, 20240321 - 酸素分子によるCu(II)-フェノラート錯体からCu(II)-フェノキシルラジカル錯体への変換反応における側鎖インドール基の効果
金城星彦; 矢島辰雄; 島崎優一
日本化学会 第104回春季年会, 2024年03月19日
20240318, 20240321 - 銅−フェノラート錯体のおはなし
島崎優一
錯体化学若⼿の会・関東⽀部勉強会, 2023年12月02日, ［招待有り］
20231202, 20231202 - p-ジメチルアミノフェノラートを配位子とする八面体型Co錯体の電子状態
金城星彦; 島崎優一
錯体化学会 第73回討論会, 2023年09月21日
20230921, 20230923 - Cu(II)-フェノラート錯体の空気酸化により生成するCu(II)-フェノキシルラジカル錯体におけるπ - π スタッキング相互作用の影響
金城星彦; 島崎優一
第２回 生命金属科学シンポジウム, 2023年05月20日
20230520, 20230521 - 〔主要な業績〕Formation of Copper(II)-Phenoxyl Radical Complexes from Copper(II)-Phenolates by O2:Characterization of Copper(I)-Phenoxyl Radical Intermediates
10th Asian Biological Inorganic Chemistry,Conference, 2022年11月30日, ［招待有り］
20221126, 20221203 - フェノキシルラジカルが配位したコバルト(II), 銅(I)錯体の性質
島 悠⼈・鈴⽊ 崇・〇島崎 優⼀
錯体化学会第72回討論会, 2022年09月26日
20220926, 20220928 - 各種高原子価金属錯体の詳細な電子状態と反応性の相関
島崎優一 ・大下宏美・鈴木 崇・星野哲久・芥川智行・谷 文都
物質・デバイス領域共同研究拠点 キックオフシンポジウム, 2022年08月08日, 大阪大学産業科学研究所, ［招待有り］
20220808 - Ni(II)-フェノラート錯体及びNi(II)-フェノール錯体と酸素分子との反応によるNi(II)-フェノキシルラジカル錯体の生成とプロトンの効果
鈴木 崇・島崎 優一
日本化学会第101回春季年会, 2021年03月 - Formation of CuII-phenoxyl Radical by Reaction of O2 with the CuII-Phenolate Complex via the CuI-Phenoxyl Radical Species
Takashi Suzuki; Yuichi SHIMAZAKI
錯体化学会第70回討論会, 2020年09月28日, ［招待有り］
20200928, 20200930 - Formation of NiII-phenoxyl radical species by O2 from the NiII-(phenol)(phenolate) complexes and their mechanisms
鈴木崇、島崎優一
錯体化学会第７０回討論会, 2020年09月30日 - 分子内酸化還元による銅(I)-フェノキシルラジカル錯体の生成と性質
島悠人; 鈴木崇; 島崎優一
錯体化学会第70回討論会, 2020年09月30日 - Oxidation Chemistry of Nickel(II)-di(phenolate) Complexes
Yuichi Shimazaki
PACIFICHEM 2015, 2015年12月14日, ［招待有り］ - Oxidation Chemistry of ,Nickel(II)-di(phenolate) Complexes
Yuichi Shimazaki
PACIFICHEM 2015, 2015年12月14日, ［招待有り］ - Characterization of One-Electron Oxidized Metal(II) Salen-type Complexes: Electronic Structure and Reactivity Relationship
Y. Shimazaki
Third International Symposium on the Photofunctional Chemistry of Complex Systems, 2015年12月12日 - Characterization of One-Electron Oxidized Metal(II) Salen-type Complexes:,Electronic Structure and Reactivity Relationship
Y. Shimazaki
Third International Symposium,on the Photofunctional Chemistry of Complex Systems, 2015年12月12日 - 金属−フェノラート錯体を酸化してみると…
島崎優一
第28回 生物無機化学夏季セミナー, 2015年08月28日, ［招待有り］ - Electronic Structures of One-Electron Oxidized Nickel(III)-Phenolate Complexes
Y. Shimazaki
EuCheMS – 2015 – Inorganic Chemistry Conference, 2015年06月28日 - Oxidation Chemistry of Metal(II)-diphenolato complexes with Salen-Type Ligands; Electronic Structure and Reactivity Relationship
Y. Shimazaki
The 3rd International Conference on Material Sciences & Engineering, 2014年10月06日, ［招待有り］ - One-electron oxidized Cu(II)-di(phenolate) complexes; Relationship between electronic structures and reactivities
Y. SHIMAZAKI
the European Biological Inorganic Chemistry Conference, 2014年08月24日 - ELECTRONIC STRUCTURES OF ONE-ELECTRON OXIDIZED NICKEL(III)-PHENOLATE COMPLEXES
Y. SHIMAZAKI
41st International Conference on Coordination Chemistry, 2014年07月21日 - One-electron oxidized Cu(II)-salen type complexes; Relationship between electronic structures and reactivities
Y. Shimazaki
The 13th Challenges in Inorganic and Materials Chemistry (ISACS13), 2014年07月01日 - Characterization and Reactivity of one-electron oxidized Cu(II)-salen-type complexes
Yuichi Shimazaki
The 11th European Biological Inorganic Chemistry Conference, 2012年09月12日 - Electronic Structures and Reactivities of Oxidized Metal(II)-salen-type Complexes
Yuichi Shimazaki
Challenges in Inorganic and Materials Chemistry 8 (ISACS8), 2012年07月19日 - Concentration dependent Pd(II)-C bond formation
Satoshi Iwatsuki; Yuichi Shimazaki
the 11th International Symposium on Applied Bioinorganic Chemistry, 2011年12月05日 - Pd(II)-C bond formation mechanism in various Pd complexes containing an indole moiety
Yuichi Shimazaki; Takuya Suzuki; Satoshi Iwatsuki; Tatsuo Yajima
5th EuCheMS NLigands Conference, 2011年09月05日 - Pd(II)-C bond formation mechanism in various Pd complexes,containing an indole moiety
Yuichi Shimazaki; Takuya Suzuki; Satoshi Iwatsuki; Tatsuo Yajima
5th EuCheMS NLigands Conference, 2011年09月05日 - Electronic Structures of Oxidized Metal(II)-salen Type Complexes Dependence with the Diamine Backbone
Yuichi Shimazaki
ICBIC15, 2011年08月11日, ［招待有り］ - Concentration-dependent Pd(II)-C bond formation in complexes with a 2N-donor ligand containing an indole moiety
Yuichi Shimazaki
18th International SPACC Symposium, 2011年08月06日, The Society of Pure and Applied Coordination Chemistry And Department of Chemistry, Simon Fraser University, ［招待有り］ - Influence of chelate effect on the electronic structure of oxidized metal(II)-di(salicylidene)diamine complexes
Yuichi Shimazaki
1st EuCheMS Inorganic Chemistry Conference, 2011年04月13日 - Characterization and electronic structures of oxidized metal(II)-salen-type complexes
PACIFICHEM 2010, 2010年12月16日, ［招待有り］ - 金属(II)salen錯体の一電子酸化体の電子構造
島崎 優一
第４回日本化学会関東支部大会, 2010年08月30日, 日本化学会関東支部, ［招待有り］ - Characterization of one-electron oxidized metal-salen type complexes (metal = Cu, Ni, Pd, and Pt)
39th International conference on Coordination Chemistry, 2010年07月27日 - Electronic structures and reactivities of oxidized metal(II)-salen-type complexes
Yuichi Shimazaki
Faraday Discussion 148: Spectroscopy Theory and mechanism in Bioinorganic chemistry, 2010年07月06日, Royal society of chemistry - Snthesis and characterization of Pd-indole complexes
Yuichi Shimazaki; Takuya Suzuki; Tatsuo Yajima; Tadashi Shiraiwa
10th European Biological Inorganic Chemistry Conference, 2010年06月24日 - Correlation of Electronic Structure and Reactivity- The Case of Oxidized Metal Salens
Osaka City University International Symposium on the Foundation of Environmentaal Research, 2010年03月10日, Osaka City University, ［招待有り］ - Characterizations and electronic structures of oxidized metal(II)-salen complexes
Yuichi Shimazaki
Gordon Research Conference, Metals in Biology, 2010年02月01日 - Characterization of One-Electron Oxidized Cu(II)-salen Type Complexes
Yuichi Shimazaki; Kazuaki Tsukidate; Tim Storr; T. Daniel; P. Stack
10th International Symposium on Applied Bioinorganic Chemistry (ISABC 10), 2009年09月28日, ［招待有り］ - マンガン錯体による水の酸化と酸素発生
島崎 優一
応用物理学会春期年会, 2009年03月, 応用物理学会, ［招待有り］ - Characterization of metal complexes containing indole rings as versatile C-donor ligands
Yuichi Shimazaki
Gordon Research Conference, Metals in Biology., 2009年01月28日 - 金属(II)-salen錯体の一電子酸化体の同定と反応性（金属＝銅、ニッケル、パラジウム、白金）
島崎 優一
有機合成化学協会第45回化学関連支部合同九州大会, 2008年07月04日, ［招待有り］ - Synthesis and Characterization of Metal Complexes Containing Biological Molecules
Yuichi Shimazaki
Lecture in Stanford University, 2008年03月, ［招待有り］ - Characterization of One-Electron Oxidized Metal-Salen Type Complexes (Metal = Cu, Ni, Pd, Pt)
Yuichi Shimazaki
Zing Conference, 2008年 - Synthesis and Characterization of Imidazolate-Bridged Polynuclear Copper Complexes
Yuichi Shimazaki
4th Europian Association for Chemystry and Molecular Science Conference, 2008年 - Oxidation Behavior of Metal-Phenolate Complexes with N3O-donor Tripodal Ligands and Characterization of Their Phenoxyl Radical Species
Yuichi Shimazaki
9th European Biological Inorganic Chemistry Conference (EUROBIC 9), 2008年 - Characterization reactivities of metal phenoxyl radical species
Yuichi Shimazaki
The 13th International Conference on Bioinorganic Chemistry (ICBIC 13), 2007年, ［招待有り］ - Structures and Oxidations of Metal phenolate Complexes.
Yuichi Shimazaki
China-Japan Crossover Science Symposium, 2007年, ［招待有り］ - A Formation and Reactivity of Indole-Binding Palladium(II) and Platinum(II) Complexes
Yuichi Shimazaki; Osamu Yamauchi
The 8th European Biological Inorganic Chemistry Conference (Eurobic 8), 2006年 - O2 evolution from a high-valent oxo-manganese porphyrin dimer.
Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
The 37th International Conference on Coordination Chemistry (ICCC 37), 2006年 - Structures and Reactivities of Metal Complexes Containing Indole Rings
Yuichi Shimazaki
Japan-China Crossover Science Symposium, 2006年, ［招待有り］ - O2 evolution from a high-valent oxo-manganese porphyrin dimer
Yuichi Shimazaki
International Conference on Bioinorganic Chemistry of the New Age, 2006年, ［招待有り］ - Characterization of a High Valent Oxo-Manganses Porphyrin Dimer : Studies Relevant to the Intermediate of a Functional Model for Oxygen Evolving Center
Yuichi Shimazaki; Taro Nagano; Hironori Takesue; Bao-Hui. Ye; Fumito Tani; Yoshinori Naruta
The 36th International Conference on Coordination Chemistry (ICCC 36), 2004年 - Indole radical formation in a Pd(II) complex involving a coordinated indole ring.
Osamu Yamauchi; Takeshi Motoyama; Yuichi Shimazaki; Tatsuo Yajima; Yasuo Nakabayashi
The 11th International Conference on Bioinorganic Chemistry (ICBIC 11), 2003年 - First isolation and crystal structure of peroxo bridged heme-copper complexes.
Takefumi Chishiro; Yuichi Shimazaki; Fumito Tani; Yochimitsu Tachi; Yoshinori Naruta; Satoru Karasawa; Sinya Hayami; Yonezo Maeda
The 11th International Conference on Bioinorganic Chemistry (ICBIC 11), 2003年 - O2 evolution from the high-valent oxo-manganese porphyrin dimer.
Yuichi Shimazaki; Taro Nagano; Hironori Takesue; Bao-Hui. Ye; Fumito Tani; Yoshinori Naruta
The 11th International Conference on Bioinorganic Chemistry (ICBIC 11), 2003年 - Characterization of a High Valent Oxo-Manganses Porphyrin Dimer : Studies Relevant to the Intermediate of a Functional Model for Oxygen Evolving Center
Yuichi Shimazaki
Gordon Reserch Conference (Organic structure and property), 2002年, ［招待有り］ - Phenoxyl Radical Formation in a Ni(II) Complex and the Temperature-Dependent Valence State.
Yuichi Shimazaki; Osamu Yamauchi
The 6th European Biological Inorganic Chemistry Conference (Eurobic 6), 2002年 - Reaction Mechanism for Water Oxidation Catalyzed by Mn-Porphyrin Dimer
Yuichi Shimazaki; Hironori Takesue; Fumito Tani; Yoshinori Naruta
The 10th International Conference on Bioinorganic Chemistry (ICBIC 10), 2001年
共同研究・競争的資金等の研究課題
社会貢献活動
学術貢献活動
- 日本化学会第 105 春季年会
パネル司会・セッションチェア等
日本化学会, 2025年03月26日 - 2025年03月29日 - 学術誌"inorganics"のEditor
監修
2024年10月01日 - 錯体化学会第73回討論会
企画立案・運営等
2022年09月 - 2023年09月 - 第10回アジア生物無機化学国際会議
企画立案・運営等
2022年01月05日 - 2022年12月03日 - Chair of session for 10th Asian Biological Inorganic Chemistry,Conference
パネル司会・セッションチェア等
2022年12月02日 - 錯体化学会第72回討論会 審査委員
審査・評価
2022年09月26日 - 第30回 金属の関与する生体関連反応シンポジウム 実行委員
企画立案・運営等
2021年01月 - 2021年07月 - 日本化学会第98回春季年会プログラム委員
企画立案・運営等
日本化学会, 2017年12月 - 2018年03月 - 日本化学会第95回春季年会プログラム委員
企画立案・運営等
日本化学会, 2014年12月 - 2015年03月 - 日本化学会第94回春季年会プログラム委員
企画立案・運営等
日本化学会, 2013年12月 - 2014年03月
