Yuichi SHIMAZAKIProfessor
■Researcher basic information
Organization
Educational Background
Career
- Apr. 2025, 茨城大学理工学研究科（理学野）化学領域 教授
- Apr. 2008 - Mar. 2025, Associate Professor in College of Science, Ibaraki University
- Apr. 2003 - Mar. 2008, Assistant Professor in Institute for Materials Chemistry and Engneering, Kyushu University
- Jun. 2001 - Mar. 2003, Assistant Professor in Institute for Fandametal Research of Organic Chemistry, Kyushu University
External link
■Research activity information
Paper
- 〔Major achievements〕Diversity of oxidation state in copper complexes with phenolate ligands
Tomoyuki Takeyama; Yuichi Shimazaki, Last, The Cu-phenolate complexes show various electronic structures, such as phenoxyl radical binding CuI complexes and CuIV–phenolate species in the formal oxidation state, which give rise to characteristic properties and reactivities of the complexes., Royal Society of Chemistry (RSC)
Dalton Transactions, Jan. 2024, [Reviewed], [Invited] - Syntheses, Characterizations, Crystal Structures, and Protonation,Reactions of Dinitrogen Chromium Complexes Supported with,Triamidoamine Ligands
Yoshiaki Kokubo; Kazuki Tsuzuki; Hikari Sugiura; Shunsuke Yomura; Yuko Wasada-Tsutsui; Tomohiro Ozawa; Sachiko Yanagisawa; Minoru Kubo; Tomoyuki Takeyama; Takahide Yamaguchi; Yuichi Shimazaki; Shinichi Kugimiya; Hideki Masuda; Yuji Kajita, American Chemical Society (ACS)
Inorganic Chemistry, Apr. 2023, [Reviewed] - 〔Major achievements〕Non-innocent redox behavior of Cu(II)-p-dimethylaminophenolate complexes: formation and characterization of the Cu(I)-phenoxyl radical species.
Yuto Shima; Takashi Suzuki; Hitoshi Abe; Tatsuo Yajima; Seiji Mori; Yuichi Shimazaki, Last
Chem. Commun., May 2022, [Reviewed] - 〔Major achievements〕Solid State Characterization of One- and Two-Electron Oxidized CuII-salen Complexes with para-Substituents: Geometric Structure-Magnetic Property Relationship
Tomoyuki Takeyama; Takashi Suzuki; Misa Kikuchi; Misato Kobayashi; Hiromi Oshita; Kyohei Kawashima; Seiji Mori; Hitoshi Abe; Norihisa Hoshino; Satoshi Iwatsuki; Yuichi Shimazaki, Last
European Journal of Inorganic Chemistry, Oct. 2021, [Reviewed] - 〔Major achievements〕Formation of the Ni(II)-Phenoxyl Radical Complexes by O2: A Mechanistic Insight into the Reaction of Ni(II)-Phenol Complexes with O2
Takashi Suzuki; Akari Sato; Hiromi Oshita; Tatsuo Yajima; Fumito Tani; Hitoshi Abe; Kaoru Mieda-Higa; Sachiko Yanagisawa; Takashi Ogura; Yuichi Shimazaki, Last,The reaction of Ni(
, Royal Society of Chemistry (RSC)ii )-(phenol)(phenolate) complexes with O2 gave the Ni(ii )-phenoxyl radical complexes assisted by CH3OH. This reaction was concluded to undergovia the proton transfer–electron transfer type mechanism without redox of the Ni ion.
Dalton Trans., Mar. 2021, [Reviewed] - Recent Advances in One-electron Oxidized CuII-Diphenoxide Complexes as Models of Galactose Oxidase: Importance of the Structural Flexibility in the Active Site
Hiromi Oshita; Yuichi Shimazaki, Last
Chem. Eur. J., 08 Jul. 2020, [Reviewed], [Invited] - Benzyl alcohol oxidation mechanisms by one- and two-electron oxidized species of Cu(II)-salen complexes with para-R-substituents, [Cu(R-salen)]n+ (R = MeO, MeS; n = 1, 2)
Corresponding
Inorganica Chimica Acta, 24 Jun. 2020, [Reviewed] - Formation of the CuII-phenoxyl radical by reaction of O2 with the CuII-phenolate complex via the CuI-phenoxyl radical
Takashi Suzuki; Hiromi Oshita; Tatsuo Yajima; Fumito Tani; Hitoshi Abe; Yuichi Shimazaki
Chem. Eur. J., Nov. 2019, [Reviewed] - The effect of pi-pi stacking interaction of the indole ring with the coordinated phenoxyl radical in a nickel (II)-salen type complex. Comparison with the corresponding Cu(II) complex
Hiromi Oshita; Takashi Suzuki; Kyohei Kawashima; Hitoshi Abe; Fumito Tani; Seiji Mori; Tatsuo Yajima; Yuichi Shimazaki
DALTON TRANSACTIONS, Aug. 2019, [Reviewed] - pi-pi Stacking Interaction in an Oxidized Cu-II-Salen Complex with a Side-Chain Indole Ring: An Approach to the Function of the Tryptophan in the Active Site of Galactose Oxidase
Hiromi Oshita; Takashi Suzuki; Kyohei Kawashima; Hitoshi Abe; Fumito Tani; Seiji Mori; Tatsuo Yajima; Yuichi Shimazaki
CHEMISTRY-A EUROPEAN JOURNAL, Jun. 2019, [Reviewed] - Electronic Structure and Reactivity Studies of a Nonsymmetric One-Electron Oxidized CuII Bis-phenoxide Complex
Linus Chiang; Erik C. Wasinger; Yuichi Shimazaki; Victor Young Jr.e Tim Storr; and T. Daniel P. Stack
Inorg. Chim. Acta, 2018, [Reviewed] - Characterization of the one-electron oxidized Cu(II)-salen complexes with a side chain aromatic ring: the effect of the indole ring on the Cu(II)-phenoxyl radical species
Hiromi Oshita; Takayoshi Yoshimura; Seiji Mori; Fumito Tani; Yuichi Shimazaki; Osamu Yamauchi
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, Jan. 2018, [Reviewed], [Invited] - Characterization of Group 10-Metal-p-Substituted Phenoxyl Radical Complexes with Schiff Base Ligands.
Hiromi Oshita; Misa Kikuchi; Kaoru Mieda; Takashi Ogura; Takayoshi Yoshimura; Fumito Tani; Tatsuo Yajima; Hitoshi Abe; Seiji Mori; Yuichi Shimazaki
CHEMISTRYSELECT, Oct. 2017, [Reviewed] - Electronic Structure Evaluation of an Oxidized Tris(methoxy)-Substituted Ni Salen Complex
Linus Chiang; Ryan M. Clarke; Khrystyna Herasymchuk; Mathew Sutherland; Kathleen E. Prosser; Yuichi Shimazaki; Tim Storr
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Jan. 2016 - Asymmetric Michael addition of thiols to beta-nitrostyrenes using a novel phenylpyrrolidine-based urea catalyst
Souichirou Kawazoe; Kazuki Yoshida; Yuichi Shimazaki; Takeshi Oriyama
Tetrahedron Letters, 2015, [Reviewed] - Properties of the indole ring in metal complexes. A comparison with the phenol ring,
Y. Shimazaki; O. Yamauchi
J. Inorg. BioChem., 2015, [Reviewed], [Invited] - Properties of the One-Electron Oxidized Copper(II) Salen-Type Complexes: Relationship between Electronic Structures and Reactivities
Yuichi Shimazaki
Pure and Applied Chemistry, 2014, [Reviewed], [Invited] - Kinetic studies on cyclopalladation in,palladium(II) complexes containing an indole,moiety
Satoshi Iwatsuki; Takuya Suzuki; Syogo Tanooka; Tatsuo Yajima and Yuichi Shimazaki
Pure and Applied Chemistry, 2014, [Reviewed], [Invited] - Characterization of One-Electron Oxidized Copper(II)-Salophen-Type Complexes; Effects of Electronic and Geometrical Structures on Reactivities
Kazutaka Asami; Akiko Takashina; Misato Kobayashi; Satoshi Iwatsuki; Tatsuo Yajima; Amélie Kochem; Maurice van Gastel; Fumito Tani; Takamitsu Kohzuma; Fabrice Thomas and Yuichi Shimazaki
Dalton Trans., 2014, [Reviewed] - FeIII Bipyrrolidine Phenoxide Complexes and Their Oxidized,Analogues
Linus Chiang; Didier Savard; Yuichi Shimazaki; Fabrice Thomas; and Tim Storr
Inorg. Chem., 2014, [Reviewed] - Symmetric Urea-Catalyzed Asymmetric Michael Addition of Thiols to β-Nitrostyrenes
Souichirou Kawazoe; Kazuki Yoshida; Yuichi Shimazaki; Takeshi Oriyama
Chem. Lett., 2014, [Reviewed] - Influence of Ligand Flexibility on the Electronic Structure of Oxidized NiIII-Phenoxide Complexes
Minoru Kawai; Takahide Yamaguchi; Shigeyuki Masaoka; Fumito Tani; Takamitsu Kohzuma; Linus Chiang; Tim Storr; Kaoru Mieda; Takashi Ogura; Robert K. Szilagyi; Yuichi Shimazaki
Inorg. Chem., 2014, [Reviewed] - Pd-C bond formation with the indole ring in palladium complexes of N,N,O-donor ligands. Effect of the nitrogen donor properties
Syogo Tanooka; Takuya Suzuki; Tatsuo Yajima; Tadashi Shiraiwa; Satoshi Iwatsuki; Yuichi Shimazaki
INORGANICA CHIMICA ACTA, Oct. 2013, [Reviewed] - Double oxidation localizes spin in a Ni bis-phenoxyl radical complex
Tim J. Dunn; Michael I. Webb; Khatera Hazin; Pratik Verma; Erik C. Wasinger; Yuichi Shimazaki and Tim Storr, Royal Society of Chemistry
Dalton Trans., 2013, [Reviewed] - Recent Advances in X-ray Structures of Metal-Phenoxyl Radical Complexes
Yuichi Shimazaki
Advances in Materials Physics and Chemistry (Review), 2013, [Reviewed], [Invited] - One-Electron Oxidized Copper(II) Salophen Complexes: Phenoxyl versus Diiminobenzene Radical Species
Amélie Kochem; Olivier Jarjayes; Benoit Baptiste; Christian Philouze; Hervé Vezin; Kazuaki Tsukidate; Fumito Tani; Maylis Orio; Yuichi Shimazaki; Fabrice Thomas
Chem. Eur. J., 2012, [Reviewed] - Supramolecular Structures of Inclusion Complexes of Cyclic Porphyrin Dimers and [6,6]-Phenyl-C 61-Butyric Acid Methyl Ester (PCBM)
Hirofumi Nobukuni; Takuya Kamimura; Hidemitsu Uno; Yuichi Shimazaki; Yoshinori Naruta; Fumito Tani
Bull. Chem. Soc. Jpn., 2012, [Reviewed] - Synthesis, Characterization, and Small Hydrocarbon Encapsulation of Dicavitand-Porphyrins
Jun Nakazawa; Jun Hagiwara; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Bull. Chem. Soc. Jpn., 2012, [Reviewed] - Synthesis and properties of charge-transfer solids with cluster units [Mo6X14]2 (X . Br, I)
Gunzi Saito; Hidemasa Hosoda; Yukihiro Yoshida; Jun Hagiwara; Kazukuni Nishimura; Hideki Yamochi; Akihiro Otsuka; Takaaki Hiramatsu; Yuichi Shimazaki; Kaplan Kirakci; Stephane Cordier; Christiane Perrin
J. Mater. Chem., 2012, [Reviewed] - Non-innocent ligand behaviour of a bimetallic Cu complex employing a bridging catecholate.
Tim J Dunn; Linus Chiang; Caterina F Ramogida; Michael I Webb; Didier Savard; Miyuki Sakaguchi; Takashi Ogura; Yuichi Shimazaki; Tim Storr
Dalton trans., 2012, [Reviewed] - Group-10 metal complexes of biological molecules and related ligands: structural and functional properties
Yuichi Shimazaki; Osamu Yamauchi
Chemistry & biodiversity(Review), 2012, [Reviewed], [Invited] - Radical Localization in a Series of Symmetric Ni(II) Complexes with Oxidized Salen Ligands.
Linus Chiang; Amélie Kochem; Olivier Jarjayes; Tim J Dunn; Hervé Vezin; Miyuki Sakaguchi; Takashi Ogura; Maylis Orio; Yuichi Shimazaki; Fabrice Thomas; Tim Storr
Chem. Eur. J., 2012, [Reviewed] - New Insights into the Electronic Structure and Reactivity of One-Electron Oxidized Copper(II)-(Disalicylidene)diamine Complexes.
Kazutaka Asami; Kazuaki Tsukidate; Satoshi Iwatsuki; Fumito Tani; Satoru Karasawa; Linus Chiang; Tim Storr; Fabrice Thomas; Yuichi Shimazaki
Inorg.Chem., 2012, [Reviewed] - Recent advances in metal-phenoxyl radical chemistry
Y. Shimazaki; O. Yamauchi
Ind. J. Chem. A. (Review), 2011, [Reviewed], [Invited] - Influence of the chelate effect on the electronic structure of one-electron oxidized group 10 metal(II)-(disalicylidene)diamine complexes
Yuichi Shimazaki; Natsumi Arai; Tim J. Dunn; Tatsuo Yajima; Fumito Tani; Caterina F. Ramogida; Tim Storr
DALTON TRANSACTIONS, 2011, [Reviewed] - Non-Innocent Ligand Behavior of a Bimetallic Ni Schiff-Base Complex Containing a Bridging Catecholate
Tim J. Dunn; Caterina F. Ramogida; Curtis Simmonds; Alisa Paterson; Edwin W. Y. Wong; Linus Chiang; Yuichi Shimazaki; and Tim Storr
Inorg. Chem., 2011, [Reviewed] - Concentration-dependent palladium(II)–indole bond formation in complexes with a 2N-donor ligand containing an indole moiety: Synthesis, characterization, and reaction analysis
Satoshi Iwatsuki; Takuya Suzuki; Tatsuo Yajima; Tadashi Shiraiwa; Osamu Yamauchi; Yuichi Shimazaki
Inorg.Chim.Acta, 2011, [Reviewed] - Supramolecular Structures of Inclusion Complexes of C70 and Cyclic Porphyrin Dimers
Hirofumi Nobukuni; Takuya Kamimura; Hidemitsu Uno; Yuichi Shimazaki; Yoshinori Naruta; Fumito Tani
Bulletin of the Chemical Society of Japan, 2011, [Reviewed] - Unprecedented formation of binuclear copper(II) complex with a perylene derived ligand by the oxidative reaction
J. Hagiwara; Y. Shimazaki; G. Saito
Inorg. Chim. Acta, 2010, [Reviewed] - Ligand Radical Localization in a Nonsymmetric One-Electron Oxidized Ni(II) Bis-phenoxide Complex
T. Storr; P. Verma; Y. Shimazaki; E. C. Wasinger; T. D. P. Stack
Chem. Eur. J., 2010, [Reviewed] - Supramolecular Structures and Photoelectronic Properties of the Inclusion Complex of a Cyclic Free-Base Porphyrin Dimer and C60
H. Nobukuni; Y. Shimazaki; H. Uno; Y. Naruta; K. Ohkubo; T. Kojima; S. Fukuzumi; S. Seki; H. Sakai; T. Hasobe and F. Tani
Chem. Eur. J., 2010, [Reviewed] - Metal Complexes involving indole rings: Structure and effects of metal-indole interaction
Yuichi Shimazaki; Tatsuo Yajima; Masako Takani; Osamu Yamauchi.
Coord. Chem. Rev., 2009, [Reviewed], [Invited] - Synthesis and Characterization of platinum(II) complexes of 2N10-donor ligands with a pendent indole ring
Yuichi Shimazaki; Tatsuo Yajima; Yasuo Nakabayashi; Yoshinori Naruta; Osamu Yamauchi.
Inorg. Chim. Acta, 2009, [Reviewed] - Zinc(II)-phenoxyl radical complexes: Dependence on complexation properties of Zn-phenolate species
Yuichi Shimazaki; Tatsuo Yajima; Tadashi Shiraiwa; Osamu Yamauchi.
Inorg. Chim. Acta, 2009, [Reviewed] - Metal complexes of amino acids and amino acid side chain groups. Structure and properties.
Yuichi Shimazaki; Masako Takani; Osamu Yamauchi
Dalton Trans.(perspective), 2009, [Reviewed], [Invited] - Detailed Evaluation of the Geometric and Electronic Structures of One-electron Oxidized Group 10 (Ni, Pd, and Pt) Metal(II)-(Disalicylidene)diamine Complexes
Yuichi Shimazaki; T. Daniel P. Stack; Tim Storr
Inorg. Chem., 2009, [Reviewed] - Anisotropic High Electron Mobility and Photodynamics of a Self-Assembled Porphyrin Nanotube including C60 Molecules
Hirofumi Nobukuni; Fumito Tani; Yuichi Shimazaki; Yoshinori Naruta; Kei Ohkubo; Tatsuaki Nakanishi; Takahiko Kojima; Shunichi Fukuzumi; Shu Seki
J. Phys. Chem. C, 2009, [Reviewed] - CH•••Metal(II) axial interaction in planar complexes (metal = Cu, Pd) and implications for possible environmental effects of alkyl groups at biological copper site
Osamu Yamauchi; Tatsuo Yajima; Rie Fujii; Yuichi Shimazaki; Masanobu Yabusaki; Masako Takani; Minoru Tashiro; Takeshi Motoyama; Mitsuhiro Kakuto; Yasuo Nakabayashi
J. InorgBio. Chem., 2008, [Reviewed] - A simple preparation of d-alloisoleucine via acetylation and separation of the ammonium salts
Tatsuo Yajima; Takao Horikawa; Nobuhiro Takeda; Eri Takemura; Hiroaki Hattori; Yuichi Shimazaki; Tadashi Shiraiwa
Tetrahedron Assymetry, 2008, [Reviewed] - Defining the Electronic and Geometric Structure of One-Electron Oxidized Copper-Bis-phenoxide Complexes
Tim Storr; Pratik Verma; Russell C. Pratt; Eric. C. Wasinger; Yuichi Shimazaki; T. Daniel P. Stack
J. Am. Chem. Soc., 2008, [Reviewed] - - Stacking assisted binding of aromatic amino acids by copper(II)-aromatic diimine complexes. Effects of ring substituents on ternary complex stability
Tatsuo Yajima; Reiko Takamido; Yuichi Shimazaki; Akira Odani; Yasuo Nakabayashi; Osamu Yamauchi
Dalton Trans., 2007, [Reviewed] - Syntheses and Electronic Structures of One-Electron-Oxidized Group 10 Metal(II)-(Disalicylidene)diamine Complexes (Metal = Ni, Pd, Pt)
Yuichi Shimazaki; Tatsuo Yajima; Fumito Tani; Satoru Karasawa; Koichi Fukui; Yoshinori Naruta; Osamu Yamauchi
J. Am. Chem. Soc., 2007, [Reviewed] - Synthesis and characterization of imidazolate-bridged polynuclear copper complexes
Takumi Higa; Masaki Moriya; Yuichi Shimazaki; Tatsuo Yajima; Fumito Tani; Satoru Karasawa; Motohiro Nakano; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chim. Acta, 2007 - Formation and Characterization of Co(III)-Semiquinonate Phenoxyl Radical Species
Yuichi Shimazaki; Ryota Kabe; Stefan Huth; Fumito Tani; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chem., 2007, [Reviewed] - A Nanotube of Cyclic Porphyrin Dimer Connected by Nonclassical Hydrogen Bonds and Its Inclusion of C60 in a Linear Arrangement
Hirofumi Nobukuni; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Angew. Chem. Int. Ed., 2007, [Reviewed] - Synthesis Crystal Structures and Single Small Molecule Encapsulation Properties of Cavitand-Porphyrin
Jun Nakazawa; Maki Mizuki; Jun Hagiwara; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Bull. Chem. Soc. Jpn., 2006, [Reviewed] - Encapsulation of Small Molecules by a Cavitand Porphyrin Self-Assenbled via Quadruple Hydrogen Bonds
Jun Nakazawa; Maki Mizuki; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Org. Lett., 2006, [Reviewed] - Selective formation of a stable mu-peroxo ferric heme-Cu-II complex from the corresponding mu-oxo Fe-III-Cu-II species with hydrogen peroxide
T Chishiro; Y Shimazaki; F Tani; Y Naruta
CHEMICAL COMMUNICATIONS, Feb. 2005, [Reviewed] - Size-Selective and Reversible Encapsulation of Single Small Hydrocarbon Molecules by a Cavitand-Porphyrin Species
Jun Nakazawa; Jun Hagiwara; Maki Mizuki; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
Angew. Chem. Int. Ed., 2005, [Reviewed] - Cyclopalladation of the Indole Ring in Palladium(II) Complexes of 2N1O Donor Ligands and Its Dependence on the O-Donor Properites
Yuichi Shimazaki; Minoru Tashiro; Takeshi Motoyama; Satoshi Iwatsuki; Tatsuo Yajima; Yasuo Nakabayashi; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chem., 2005, [Reviewed] - Characterization of Dinuclear MnV=O Complex and Its Efficient O2 Evolution in the Presence of Water
Yuichi Shimazaki; Taro Nagano; Hironori Takesue; Bao-Hui Ye; Fumito Tani; Yoshinori Naruta
Angew. Chem. Int. Ed., 2004, [Reviewed] - Reactivity of the Indole Ring in Palladium(II) Complexes of 2N1O-Donor Ligands: Cyclopalladation and -Cation Radical Formation
Takeshi Motoyama; Yuichi Shimazaki; Tatsuo Yajima; Yasuo Nakabayashi; Yoshinori Naruta; Osamu Yamauchi
J. Am. Chem. Soc., 2004, [Reviewed] - Nickel(II)-Phenoxyl Radical Complexes: Structure-Radical Stability Relationship
Yuichi Shimazaki; Stefan Huth; Satoru Karasawa; Shun Hirota; Yoshinori Naruta; Osamu Yamauchi
Inorg. Chem., 2004, [Reviewed] - Intramolecular Rearrangement for Regioselective Complexation Delived from Intramolecular CH/ Interaction in a Hydrophobic Ruthenium Coordination Sphere
Takahiko Kojima; Sousi Miyazaki; Ken-ichi Hayashi; Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta; Yoshihisa Maeda
Chem. Eur. J., 2004, [Reviewed] - An Active-Site Model of Prostaglandin H Synthase: Iron “Twin Coronet” Porphyrin with an Aryloxyl Radical and Its Catalytic Oxygenation of 1,4-Diene
Eiki Matsui; Yoshinori Naruta; Fumito Tani; Yuichi Shimazaki
Angew. Chem. Int. Ed., 2003 - Isolation and Crystal Structure of a Peroxo-Bridged Heme-Copper Complex
Takefumi Chishiro; Yuichi Shimazaki; Fumito Tani; Yoshimitzu Tachi; Yoshinori Naruta; Satoru Karasawa; Shinya Hayami; Yonezo Maeda
Angew. Chem. Int. Ed., 2003, [Reviewed] - One-electron Oxidized Nickel(II)-Di(salicylidene)diamine Complexes: Temperature Dependent Tautomerism between Ni(III)-Phenolate and Ni(II)-Phenoxyl Radical States
Yuichi Shimazaki; Fumito Tani; Koichi Fukui; Yoshinori Naruta; Osamu Yamauchi
J. Am. Chem. Soc., 2003, [Reviewed] - Studies on galactose oxidase active site model complexes:effects of ring substituents on Cu(II)-phenoxyl radical formation
Yuichi Shimazaki; Stefan Huth; Shun Hirota; Osamu Yamauchi
Inorg. Chim. Acta, 2002, [Reviewed] - Conformational preference of the side chain aromatic ring in Cu(II) and Pd(II) complexes of 2N1O-donor ligands
Tatsuo Yajima; Yuichi Shimazaki; Naoya Ishigami; Akira Odani; Osamu Yamauchi
Inorg. Chim. Acta, 2002, [Reviewed] - Synthesis and Characterization of the Dicobalt Bisporphyrin Complex Linked by 1, 2-phenylene Bridged
Yuichi Shimazaki; Hironori Takesue; Takefumi Chishiro; Fumito Tani; Yoshinori Naruta
Chem. Lett., 2001, [Reviewed] - Effects of a Side Chain Aromatic Ring on the Reactivity of Copper(I) complexes with Dioxygen
Yuichi Shimazaki; Takeo Nogami; Fumito Tani; Akira Odani; Osamu Yamauchi
Angew. Chem. Int. Ed., 2001, [Reviewed] - 2-(Imidazol-1-yl)-4-methylphenol
Yoshinori Naruta; Yoshimitzu Tachi; Takefumi Chishiro; Yuichi Shimazaki; Fumito Tani
Acta Crystallogr., Sect E, 2001, [Reviewed] - Chemical Approach to the Cu(II)-Phenoxyl Radical Site in Galactose Oxidase: Dependence of the Radical Stability on N-Donor Properties
Yuichi Shimazaki; Stefan Huth; Shun Hirota; Osamu Yamauchi
Bull. Chem. Soc. Jpn., 2000, [Reviewed] - A Structure Model for Galactose Oxidase Active Site and Counteranion-Dependent Phenoxyl Radical Formation by Disproportionation
Yuichi Shimazaki; Stefan Huth; Akira Odani; Osamu Yamauchi
Angew. Chem. Int. Ed., 2000, [Reviewed] - Synthesis and Characterization of Imidazolate-Bridged Dinuclear Complexes as Active Site Models of Cu,Zn-SOD
Hideki Ohtsu; Yuichi Shimazaki; Akira Odani; Osamu Yamauchi; Wasuke Mori; Shinobu Itoh; Shunichi Fukuzumi
J. Am. Chem. Soc., 2000, [Reviewed] - Chemical Approach to the Cu(II)-Phenoxyl Radical Site in A novel imidazolate-bridged copper-zinc heterodinuclear complex as a Cu,Zn-SOD active site model
Hideki Ohtsu; Yuichi Shimazaki; Akira Odani; Osamu Yamauchi
Chem. Commun., Dec. 1999, [Reviewed] - Copper(I) Complexes with a Prooxymal Aromatic Ring: Novel Copper-Indole Bonding
Yuichi Shimazaki; Hiroshi Yokoyama; Osamu Yamauchi
Angew. Chem. Int. Ed., 1999, [Reviewed]
MISC
- One-electron oxidized Cu(II)-di(phenolate) complexes; Relationship between electronic structures and reactivities
Yuichi Shimazaki
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, Aug. 2014 - フラーレン類を包接した環状ポルフィリン二量体の超分子構造とその光・電子物性
信国浩文; 谷文都; 島崎優一; 成田吉徳; 大久保敬; 中西達昭; 小島隆彦; 福住俊一; 関修平; 宇野英満
基礎有機化学討論会要旨集, 18 Sep. 2009 - INOR 757-Investigation of the locus of oxidation and spectroscopic features of oxidized copper and nickel bis-phenoxide complexes
Tim Storr; Erik C. Wasinger; Russell Pratt; Yuichi Shimazaki; T. Daniel P. Stack
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2008
Books and other publications
- 〔Major achievements〕大学生 これから学ぶ化学
速水真也・黒岩敬太・島崎優一・大久保貴志・折山 剛・西野 宏・須藤 篤, Joint work
培風館, 19 May 2023
9784563046422 - 錯体化合物事典
島崎優一, Contributor
朝倉書店, 10 Sep. 2019
9784254141054 - Recent Advances in the Field of Phenoxyl Radical–Metal Complexes in The Chemistry of Metal Phenolates (Volume 2)
Yuichi Shimazaki, Joint work
John Wiley & Sons, Ltd, 19 Sep. 2016 - The Chemistry of Metal-Phenolates
Yuichi Shimazaki (Ed. J. Zabicky ), Single work
John Wiley & Sons, Ltd, 04 Apr. 2014
9780470973585 - Electrochemistry
Single work
INTECH, Feb. 2013 - ベーシックマスター 無機化学
増田秀樹; 長嶋雲兵, Joint work
オーム社, 15 Oct. 2010
9784274209215
Lectures, oral presentations, etc.
- 酸素分子を用いた銅(II)-フェノキシド錯体の酸化反応にみられる側鎖インドール基の分子内相互作用による安定化
三輪百々花; 金城星彦; 島崎優一
日本化学会第 105 春季年会, 28 Mar. 2025
20250326, 20250329 - 銅(II)-フェノキシルラジカル錯体による第一級アルコールの触媒的酸化とその反応機構
吉井万里奈; 島崎優一
日本化学会第 105 春季年会, 27 Mar. 2025
20250326, 20250329 - 酸素分子による銅(II)-フェノキシルラジカル錯体を触媒としたベンジルアルコールの酸化触媒の構築
吉井 万里奈; 島崎 優一
第57回酸化反応討論会, 16 Nov. 2024
20241116, 20241117 - Reaction of Cu(II)-phenolate with O2: Formation of Cu(II)-phenoxyl radical via the Cu(I)-phenoxyl radical species
Yuichi ShImazaki
The 17th European Biological Inorganic Chemistry Conference (EuroBIC-17), 27 Aug. 2024
20240825, 20240929 - Valence isomerization of Co complexes with a p-dimethylaminophenolate ligand
Hoshihiko Kaneshiro; Yuichi Shimazaki
The 74th Conference of Japan Society of Coordination Chemistry, 20 Sep. 2024
20240918, 20240920 - The role of a side-chain indole group for formation of Cu(II)-phenoxyl radical by Cu(II)-phenolate and O2
Hoshihiko Kaneshiro; Yuichi Shimazaki
The 17th European Biological Inorganic Chemistry Conference (EuroBIC-17), 26 Aug. 2024
20240825, 20240829 - 大気下における銅(II) -フェノキシルラジカル錯体を用いた第一級アルコールの触媒的酸化
吉井 万里奈; 島崎 優一
日本化学会 第104回春季年会, 20 Mar. 2024
20240318, 20240321 - 酸素分子によるCu(II)-フェノラート錯体からCu(II)-フェノキシルラジカル錯体への変換反応における側鎖インドール基の効果
金城星彦; 矢島辰雄; 島崎優一
日本化学会 第104回春季年会, 19 Mar. 2024
20240318, 20240321 - 銅−フェノラート錯体のおはなし
島崎優一
錯体化学若⼿の会・関東⽀部勉強会, 02 Dec. 2023, [Invited]
20231202, 20231202 - p-ジメチルアミノフェノラートを配位子とする八面体型Co錯体の電子状態
金城星彦; 島崎優一
錯体化学会 第73回討論会, 21 Sep. 2023
20230921, 20230923 - Cu(II)-フェノラート錯体の空気酸化により生成するCu(II)-フェノキシルラジカル錯体におけるπ - π スタッキング相互作用の影響
金城星彦; 島崎優一
第２回 生命金属科学シンポジウム, 20 May 2023
20230520, 20230521 - 〔Major achievements〕Formation of Copper(II)-Phenoxyl Radical Complexes from Copper(II)-Phenolates by O2:Characterization of Copper(I)-Phenoxyl Radical Intermediates
10th Asian Biological Inorganic Chemistry,Conference, 30 Nov. 2022, [Invited]
20221126, 20221203 - フェノキシルラジカルが配位したコバルト(II), 銅(I)錯体の性質
島 悠⼈・鈴⽊ 崇・〇島崎 優⼀
錯体化学会第72回討論会, 26 Sep. 2022
20220926, 20220928 - 各種高原子価金属錯体の詳細な電子状態と反応性の相関
島崎優一 ・大下宏美・鈴木 崇・星野哲久・芥川智行・谷 文都
物質・デバイス領域共同研究拠点 キックオフシンポジウム, 08 Aug. 2022, 大阪大学産業科学研究所, [Invited]
20220808 - Ni(II)-フェノラート錯体及びNi(II)-フェノール錯体と酸素分子との反応によるNi(II)-フェノキシルラジカル錯体の生成とプロトンの効果
鈴木 崇・島崎 優一
日本化学会第101回春季年会, Mar. 2021 - Formation of CuII-phenoxyl Radical by Reaction of O2 with the CuII-Phenolate Complex via the CuI-Phenoxyl Radical Species
Takashi Suzuki; Yuichi SHIMAZAKI
錯体化学会第70回討論会, 28 Sep. 2020, [Invited]
20200928, 20200930 - Formation of NiII-phenoxyl radical species by O2 from the NiII-(phenol)(phenolate) complexes and their mechanisms
鈴木崇; 島崎優一
錯体化学会第７０回討論会, 30 Sep. 2020 - 分子内酸化還元による銅(I)-フェノキシルラジカル錯体の生成と性質
島悠人; 鈴木崇; 島崎優一
錯体化学会第70回討論会, 30 Sep. 2020 - Oxidation Chemistry of Nickel(II)-di(phenolate) Complexes
Yuichi Shimazaki
PACIFICHEM 2015, 14 Dec. 2015, [Invited] - Oxidation Chemistry of ,Nickel(II)-di(phenolate) Complexes
Yuichi Shimazaki
PACIFICHEM 2015, 14 Dec. 2015, [Invited] - Characterization of One-Electron Oxidized Metal(II) Salen-type Complexes: Electronic Structure and Reactivity Relationship
Y. Shimazaki
Third International Symposium on the Photofunctional Chemistry of Complex Systems, 12 Dec. 2015 - Characterization of One-Electron Oxidized Metal(II) Salen-type Complexes:,Electronic Structure and Reactivity Relationship
Y. Shimazaki
Third International Symposium,on the Photofunctional Chemistry of Complex Systems, 12 Dec. 2015 - 金属−フェノラート錯体を酸化してみると…
島崎優一
第28回 生物無機化学夏季セミナー, 28 Aug. 2015, [Invited] - Electronic Structures of One-Electron Oxidized Nickel(III)-Phenolate Complexes
Y. Shimazaki
EuCheMS – 2015 – Inorganic Chemistry Conference, 28 Jun. 2015 - Oxidation Chemistry of Metal(II)-diphenolato complexes with Salen-Type Ligands; Electronic Structure and Reactivity Relationship
Y. Shimazaki
The 3rd International Conference on Material Sciences & Engineering, 06 Oct. 2014, [Invited] - One-electron oxidized Cu(II)-di(phenolate) complexes; Relationship between electronic structures and reactivities
Y. SHIMAZAKI
the European Biological Inorganic Chemistry Conference, 24 Aug. 2014 - ELECTRONIC STRUCTURES OF ONE-ELECTRON OXIDIZED NICKEL(III)-PHENOLATE COMPLEXES
Y. SHIMAZAKI
41st International Conference on Coordination Chemistry, 21 Jul. 2014 - One-electron oxidized Cu(II)-salen type complexes; Relationship between electronic structures and reactivities
Y. Shimazaki
The 13th Challenges in Inorganic and Materials Chemistry (ISACS13), 01 Jul. 2014 - Characterization and Reactivity of one-electron oxidized Cu(II)-salen-type complexes
Yuichi Shimazaki
The 11th European Biological Inorganic Chemistry Conference, 12 Sep. 2012 - Electronic Structures and Reactivities of Oxidized Metal(II)-salen-type Complexes
Yuichi Shimazaki
Challenges in Inorganic and Materials Chemistry 8 (ISACS8), 19 Jul. 2012 - Concentration dependent Pd(II)-C bond formation
Satoshi Iwatsuki and Yuichi Shimazaki
the 11th International Symposium on,Applied Bioinorganic Chemistry, 05 Dec. 2011 - Pd(II)-C bond formation mechanism in various Pd complexes containing an indole moiety
Yuichi Shimazaki; Takuya Suzuki; Satoshi Iwatsuki; Tatsuo Yajima
5th EuCheMS NLigands Conference, 05 Sep. 2011 - Pd(II)-C bond formation mechanism in various Pd complexes,containing an indole moiety
Yuichi Shimazaki; Takuya Suzuki; Satoshi Iwatsuki; Tatsuo Yajima
5th EuCheMS NLigands Conference, 05 Sep. 2011 - Electronic Structures of Oxidized Metal(II)-salen Type Complexes Dependence with the Diamine Backbone
Yuichi Shimazaki
ICBIC15, 11 Aug. 2011, [Invited] - Concentration-dependent Pd(II)-C bond formation in complexes with a 2N-donor ligand containing an indole moiety
Yuichi Shimazaki
18th International SPACC Symposium, 06 Aug. 2011, The Society of Pure and Applied Coordination Chemistry And,Department of Chemistry, Simon Fraser University, [Invited] - Influence of chelate effect on the electronic structure of oxidized metal(II)-di(salicylidene)diamine complexes
Yuichi Shimazaki
1st EuCheMS Inorganic Chemistry Conference, 13 Apr. 2011 - Characterization and electronic structures of oxidized metal(II)-salen-type complexes
PACIFICHEM 2010, 16 Dec. 2010, [Invited] - 金属(II)salen錯体の一電子酸化体の電子構造
島崎 優一
第４回日本化学会関東支部大会, 30 Aug. 2010, 日本化学会関東支部, [Invited] - Characterization of one-electron oxidized metal-salen type complexes (metal = Cu, Ni, Pd, and Pt)
39th International conference on Coordination Chemistry, 27 Jul. 2010 - Electronic structures and reactivities of oxidized metal(II)-salen-type complexes
Yuichi Shimazaki
Faraday Discussion 148: Spectroscopy Theory and mechanism in Bioinorganic chemistry, 06 Jul. 2010, Royal society of chemistry - Snthesis and characterization of Pd-indole complexes
Yuichi Shimazaki; Takuya Suzuki; Tatsuo Yajima; and Tadashi Shiraiwa
10th European Biological Inorganic Chemistry Conference, 24 Jun. 2010 - Correlation of Electronic Structure and Reactivity- The Case of Oxidized Metal Salens
Osaka City University International Symposium on the Foundation of Environmentaal Research, 10 Mar. 2010, Osaka City University, [Invited] - Characterizations and electronic structures of oxidized metal(II)-salen complexes
Yuichi Shimazaki
Gordon Research Conference, Metals in Biology, 01 Feb. 2010 - Characterization of One-Electron Oxidized Cu(II)-salen Type Complexes
Yuichi Shimazaki; Kazuaki Tsukidate; Tim Storr; T. Daniel P. Stack
10th International Symposium on Applied Bioinorganic Chemistry (ISABC 10), 28 Sep. 2009, [Invited] - マンガン錯体による水の酸化と酸素発生
島崎 優一
応用物理学会春期年会, Mar. 2009, 応用物理学会, [Invited] - Characterization of metal complexes containing indole rings as versatile C-donor ligands
Yuichi Shimazaki
Gordon Research Conference, Metals in Biology., 28 Jan. 2009 - 金属(II)-salen錯体の一電子酸化体の同定と反応性（金属＝銅、ニッケル、パラジウム、白金）
Yuichi Shimazaki
有機合成化学協会第45回化学関連支部合同九州大会, 04 Jul. 2008, [Invited] - Synthesis and Characterization of Metal Complexes Containing Biological Molecules
Yuichi Shimazaki
Lecture in Stanford University, Mar. 2008, [Invited] - Characterization of One-Electron Oxidized Metal-Salen Type Complexes (Metal = Cu, Ni, Pd, Pt)
Yuichi Shimazaki
Zing Conference, 2008 - Synthesis and Characterization of Imidazolate-Bridged Polynuclear Copper Complexes
Yuichi Shimazaki.
4th Europian Association for Chemystry and Molecular Science Conference, 2008 - Oxidation Behavior of Metal-Phenolate Complexes with N3O-donor Tripodal Ligands and Characterization of Their Phenoxyl Radical Species
Yuichi Shimazaki
9th European Biological Inorganic Chemistry Conference (EUROBIC 9), 2008 - Characterization reactivities of metal phenoxyl radical species
Yuichi Shimazaki
The 13th International Conference on Bioinorganic Chemistry (ICBIC 13), 2007, [Invited] - Structures and Oxidations of Metal phenolate Complexes.
Yuichi Shimazaki
China-Japan Crossover Science Symposium, 2007, [Invited] - A Formation and Reactivity of Indole-Binding Palladium(II) and Platinum(II) Complexes
Yuichi Shimazaki; Osamu Yamauchi.
The 8th European Biological Inorganic Chemistry Conference (Eurobic 8), 2006 - O2 evolution from a high-valent oxo-manganese porphyrin dimer.
Yuichi Shimazaki; Fumito Tani; Yoshinori Naruta
The 37th International Conference on Coordination Chemistry (ICCC 37), 2006 - Structures and Reactivities of Metal Complexes Containing Indole Rings
Yuichi Shimazaki
Japan-China Crossover Science Symposium, 2006, [Invited] - O2 evolution from a high-valent oxo-manganese porphyrin dimer
Yuichi Shimazaki
International Conference on Bioinorganic Chemistry of the New Age, 2006, [Invited] - Characterization of a High Valent Oxo-Manganses Porphyrin Dimer : Studies Relevant to the Intermediate of a Functional Model for Oxygen Evolving Center
Yuichi Shimazaki; Taro Nagano; Hironori Takesue; Bao-Hui. Ye; Fumito Tani; Yoshinori Naruta
The 36th International Conference on Coordination Chemistry (ICCC 36), 2004 - Indole radical formation in a Pd(II) complex involving a coordinated indole ring.
Osamu Yamauchi; Takeshi Motoyama; Yuichi Shimazaki; Tatsuo Yajima; Yasuo Nakabayashi
The 11th International Conference on Bioinorganic Chemistry (ICBIC 11), 2003 - First isolation and crystal structure of peroxo bridged heme-copper complexes.
Takefumi Chishiro; Yuichi Shimazaki; Fumito Tani; Yochimitsu Tachi; Yoshinori Naruta; Satoru Karasawa; Sinya Hayami; Yonezo Maeda
The 11th International Conference on Bioinorganic Chemistry (ICBIC 11), 2003 - O2 evolution from the high-valent oxo-manganese porphyrin dimer.
Yuichi Shimazaki; Taro Nagano; Hironori Takesue; Bao-Hui. Ye; Fumito Tani; Yoshinori Naruta
The 11th International Conference on Bioinorganic Chemistry (ICBIC 11), 2003 - Characterization of a High Valent Oxo-Manganses Porphyrin Dimer : Studies Relevant to the Intermediate of a Functional Model for Oxygen Evolving Center
Yuichi Shimazaki
Gordon Reserch Conference (Organic structure and property), 2002, [Invited] - Phenoxyl Radical Formation in a Ni(II) Complex and the Temperature-Dependent Valence State.
Yuichi Shimazaki; Osamu Yamauchi
The 6th European Biological Inorganic Chemistry Conference (Eurobic 6), 2002 - Reaction Mechanism for Water Oxidation Catalyzed by Mn-Porphyrin Dimer
Yuichi Shimazaki; Hironori Takesue; Fumito Tani; Yoshinori Naruta
The 10th International Conference on Bioinorganic Chemistry (ICBIC 10), 2001
Affiliated academic society
Research Themes
- 各種高原子価金属錯体の詳細な電子状態と反応性の相関
Apr. 2021 - Mar. 2026 - 金属イオンを用いたフェノールの酸化とその機構に関する研究
Jun. 2022 - Mar. 2023 - 金属イオンを用いたフェノールの酸化とその機構に関する研究
Apr. 2021 - Mar. 2022 - 金属錯体の酸化状態制御と特異的反応性に関する研究
Apr. 2019 - Mar. 2022 - Formation and Characterization of metal-phenoxyl radical complexes by air oxidation; properties and reactivities relationship
基盤研究(C)
Apr. 2016 - Mar. 2019 - Characterization and reactivity of nickel(IV) and copper(IV) complexes and their oxidation state equivalents
Grant-in-Aid for Scientific Research (C)
Ibaraki University
01 Apr. 2013 - 31 Mar. 2016 - Relationship between electronic structure and reactivity of various high-valent metal complexes
Grant-in-Aid for Scientific Research (C)
Ibaraki University
2010 - 2012 - Synthesis of Molecular Catalysts for Interconversion between Water and Oxygen
Grant-in-Aid for Scientific Research (S)
Kyushu University
2005 - 2009 - Development of New Molecular Catalysts for Dioxygen Activation and Biomimetic Fuel Cell
Grant-in-Aid for Scientific Research (A)
KYUSHU UNIVERSITY
2002 - 2004 - New Oxygen Activation Reaction with Rationally Designed Metal Complexes
Grant-in-Aid for Scientific Research on Priority Areas
Kyushu University
1999 - 2002
Social Contribution Activities
Academic Contribution Activities
- 日本化学会第 105 春季年会
Panel chair etc
日本化学会, 26 Mar. 2025 - 29 Mar. 2025 - 学術誌"inorganics"のEditor
Supervision
01 Oct. 2024 - 錯体化学会第73回討論会
Planning etc
Sep. 2022 - Sep. 2023 - 第10回アジア生物無機化学国際会議
Planning etc
05 Jan. 2022 - 03 Dec. 2022 - Chair of session for 10th Asian Biological Inorganic Chemistry,Conference
Panel chair etc
02 Dec. 2022 - 錯体化学会第72回討論会 審査委員
Review
26 Sep. 2022 - 第30回 金属の関与する生体関連反応シンポジウム 実行委員
Planning etc
Jan. 2021 - Jul. 2021 - 日本化学会第98回春季年会プログラム委員
Planning etc
日本化学会, Dec. 2017 - Mar. 2018 - 日本化学会第95回春季年会プログラム委員
Planning etc
日本化学会, Dec. 2014 - Mar. 2015 - 日本化学会第94回春季年会プログラム委員
Planning etc
日本化学会, Dec. 2013 - Mar. 2014
